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Recent advances in marine electromagnetic surveys have allowed geophysicists to interpret and map offshore freshwater resources with unprecedented resolution and to test inferences regarding onshore-offshore hydrologic connections. To date, however, little is known about the timing or isotopic composition of this unconventional water resource. Here, we reconstructed the Pleistocene hydrogeology of the U.S. Atlantic continental shelf using a cross-sectional paleo-hydrogeologic model to explore possible mechanisms and timing of freshwater emplacement offshore Martha’s Vineyard, Massachusetts. We considered two scenarios in which the Laurentide ice sheet extended different distances offshore, and a third scenario without any ice sheet. The hydrostratigraphic framework was constructed by integrating borehole lithology data, seismic data, and formation resistivity data. Model results were compared to formation resistivity data as well as borehole salinity, groundwater residence time, and stable isotope profiles. Neither of the ice-sheet scenarios provided a significantly better fit to the onshore isotopic and offshore salinity observations than the third scenario. All three model scenarios predicted freshwater emplacement within Tertiary and Cretaceous units. Pleistocene deposits were largely devoid of freshened groundwater. Simulated groundwater residence times for the midshelf region ranged between 104 and 106 yr at depths of <500 m. Simulated groundwater ages from wells completed within Pleistocene confined aquifers are consistent with measured groundwater ages within confined aquifers of Martha’s Vineyard and Nantucket Island (2750−5900 yr). Analysis of onshore 3H/3He dating data indicates that some wells contain a mixture of old and modern (<60 yr) groundwater. Calculated fossil groundwater in the midshelf region that included ice-sheet loading retained relatively low δ18O values, consistent with glacial meltwater recharge. Model results suggest that much of the freshwater emplacement occurred within the last glacial cycle and that the island and offshore hydrogeologic systems appear to be connected. 

The Paradox Basin in the Colorado Plateau (USA) has some of the most iconic records of paleofluid flow, including sandstone bleaching and ore mineralization, and hydrocarbon, CO2, and He reservoirs, yet the sources of fluids responsible for these extensive fluid-rock reactions are highly debated. This study, for the first time, characterizes fluids within the basin to constrain the sources and emergent behavior of paleofluid flow resulting in the iconic rock records. Major ion and isotopic (δ18Owater; δDwater; δ18OSO4; δ34SSO4; δ34SH2S; 87Sr/86Sr) signatures of formation waters were used to evaluate the distribution and sources of fluids and water-rock interactions by comparison with the rock record. There are two sources of salinity in basinal fluids: (1) diagenetically altered highly evaporated paleo-seawater-derived brines associated with the Pennsylvanian Paradox Formation evaporites; and (2) dissolution of evaporites by topographically driven meteoric circulation. Fresh to brackish groundwater in the shallow Cretaceous Burro Canyon Formation contains low Cu and high SO4 concentrations and shows oxidation of sulfides by meteoric water, while U concentrations are higher than within other formation waters. Deeper brines in the Pennsylvanian Honaker Trail Formation were derived from evaporated paleo-seawater mixed with meteoric water that oxidized sulfides and dissolved gypsum and have high 87Sr/86Sr indicating interaction with radiogenic siliciclastic minerals. Upward migration of reduced (hydrocarbon- and H2S-bearing) saline fluids from the Pennsylvanian Paradox Formation along faults likely bleached sandstones in shallower sediments and provided a reduced trap for later Cu and U deposition. The distribution of existing fluids in the Paradox Basin provides important constraints to understand the rock record over geological time.